If you'd like to learn how to start from the absolute beginning, click here. Otherwise I'll assume you've gotten all the way through the download. It's also important that you know what version you're on, though it's more of a preference. First things first, Twine is a set of passages, a Stylesheet, and Javascript. You can move between passages via links. Links in their most basic form look like this.
[[samplepassage]]
This is a direct link to another passage of the same name. You can append this to link to a different passage than the text implies.
[[Use the door.|Door2]]
Or
[[Use the door.-$gt;Door2]]
Anything more complicated involves macros.
With words:
<<link "Excalibur">><<set $Excalibur to true>></link>
An ''EXTREMELY'' important part about links is making sure you have your brackets right. Macros utilize two <<>>, while regular HTML might only use <>. You'll make this mistake at least once.
Basic links can't be styled through CSS.
p { color: red; }
body { background-color: #eee; }